Why Energy Bands Form
In a crystal, valence electrons are shared by more than one atom due to interatomic interaction. This causes splitting of energy levels. The collection of these closely spaced energy levels is called an Energy Band.
Inside the crystal, each electron has a unique position and no two electrons have exactly the same pattern of surrounding charges — leading to different energy levels.
Valence Band
The band including energy levels of the valence electrons. May be partially or completely filled, but never empty. Does not contribute to electric current.
Conduction Band
The band above the valence band. At room temperature, it is either empty or partially filled. This band contributes to electric current.
Energy Band Gap (Eg)
Minimum energy required to shift electrons from valence to conduction band. It is the gap between the top of valence band and bottom of conduction band.